The "Gossip Girl" actress worked the arrivals in the big music show in Nashville, Tennessee before heading inside to grab a seat first before the show start time of 20:00 in the chain ABC.
Set on stage during the CMA annual performances are a complete list of the biggest names including Gwyneth Paltrow, Taylor Swift, Sheryl Crow, Miranda Lambert, Carrie Underwood and Keith Urban, just to name a few.
Meanwhile, the show is again co-hosted by Brad Paisley and Carrie Underwood - marking the third year in a row, the duo was in charge of the country showcase increasingly popular.
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